From Dehumidification to Siloxane: Parker Biogas Purification - The Importance of Removing Contaminants from Biogas
Biogas Production and Utilization
Biogas is an extremely valuable energy source. Originating from biomass, sewage, plants and landfill sites, it is gaining ever-increasing worldwide recognition as a premium source of renewable energy. It is also making a major contribution to the global energy supply mix by replacing existing fossil-fuel sources such as coal, oil and conventional natural gas.
In biogas production plants, anaerobic digestion is a process that occurs when microorganisms decompose the organic content of the feedstock in the absence of oxygen to generate raw biogas. The principle constituents of raw biogas are methane and carbon dioxide, with other trace gases also present in differing amounts depending on the feedstock and digestion process.
The characteristics of biogas are comparable to natural gas in that the methane concentration defines the energy content of the gas—the higher the methane content, the higher the calorific energy value of the gas.
The most common method of using biogas for energy production is through combustion in a gas engine or turbine to generate a combination of heat and electrical power (CHP). Biogas can also be upgraded, which essentially entails the removal of CO2, to produce biomethane (also known as renewable natural gas), which is equivalent to conventional natural gas (CNG) and can be injected into the gas grid or used as a vehicle fuel.
Raw Biogas Treatment
Most of today’s digestion processes produce biogas that is saturated with water vapor and contains varying degrees of other impurities. These impurities may cause corrosion, deposits and damage to equipment, and they should be removed before biogas is used to produce energy.
Gaseous constituents that should be removed (or reduced) along with water vapor include hydrogen sulphide, halogen compounds (chlorides, fluorides), ammonia, siloxanes and volatile organic compounds (VOCs). Biogas also contains dust and dirt particles, which should also be removed as part of the raw biogas treatment process.
The selection of an effective biogas treatment is therefore particularly important, especially for optimizing the cogeneration of electrical and thermal energy, making the most of the available renewable energy, reducing energy consumption, and keeping operating costs to a minimum.
Biogas particulate prefilter and filter element
Biogas Particulate Prefiltration
Biogas produced in anaerobic digesters and landfills contain foams, small solid particles in suspension, greases, particulates and other contaminants that must be removed from the gas by filtration prior to any downstream equipment or pipework. Failure to remove these impurities may lead to a malfunction of devices and processes downstream.
It is beneficial for all biogas production systems to install a coarse particulate filter (around 25 micron is optimal) as a first line of protection for all downstream equipment.
A well designed particulate filter for raw biogas should combine particle retention efficiency with extremely low pressure-drop to produce clean, ready-to-use biogas, while minimizing service costs. It is also imperative that the materials of construction, principally the housing and the filter element, are resistant to the aggressive contaminants in the gas.
It is generally accepted that a reduction in water content is beneficial to the CHP system, however, traditional methods, such as condensate traps and underground pipework, cannot achieve low dew points, consequently reducing the benefit of removing water. For underground pipework alone to have any real cooling effect, long runs of pipe are necessary, which is often impractical, expensive, and difficult to maintain and service.
It is also common to use “air conditioning” type chillers for biogas cooling, but these units are not designed to produce low-temperature water. They either result in higher gas dew points or end up operating well outside of their design limits, resulting in higher energy consumption and reduced service life.
It is therefore essential to use a cooling system, such as those in the Parker BioEnergy range, specifically designed to produce low dew points and operate in aggressive ambient conditions, such as those experienced in biogas applications.
Particulate prefilters can prevent pipescale from fouling heat exchangers
The 4 Major Benefits of Dehumidifying Biogas
There are four major benefits of dehumidifying biogas. It will increase the energy content of gas, prevent the corrosion of pipework and system components, partially removes or reduces concentrations of specific gases, and complies with instructions from major gas engine suppliers.
1. Increases Energy Content of Gas
Raw biogas usually has a very high water vapor content (between 30 and 100 g water per m³ gas), which equates to between 4 and 8 percent of the total gas composition and reduces the calorific value of the gas. Drying biogas to a dew point of 5°C reduces the moisture content to 1 percent, thus increasing the methane content by around 5 percent. This, in turn, increases the calorific value of the gas.
2. Prevents Corrosion of Pipework and System Components
When ambient temperature drops, the gas cools, causing water vapor to condense in the pipeline. Condensate can combine with CO2, hydrogen sulfide (H2S), etc. to form an acidic compound that causes the accelerated corrosion of machines, gas scrubbers, pipelines, buffer vessels, sensors and instruments. The combination of H2S and water produces sulphuric acid and/or ionic hydrogen, and the combination of CO2 and water produces carbonic acid. The resulting acidic condensate is highly corrosive and will cause a rapid drop in the alkalinity of the engine oil. Drying the gas to a low dew point ensures that water vapor does not condense, thereby preventing the production of these corrosive acids.
3. Partially Removes H2S, Ammonia, Siloxanes and Other Water-Soluble Gases
With efficient dehumidification, it is possible not only to remove the water vapor, but also to reduce the concentration of components, such as H2S, siloxanes, ammonia and halogen compounds, each of which dissolves in the condensed water. The partial or complete removal of these contaminants improves the efficiency of the whole plant and greatly reduces maintenance costs and plant downtime.
4. Complies with Technical Instruction of Major Gas Engine Suppliers
Unlike petrol and diesel fuels, gaseous fuels generally do not have to comply with strict quality specifications. For this reason, the manufacturers of cogeneration engines issue technical instructions to ensure the fuel gas is of sufficient quality to prevent any negative effects on engine performance and service life.
In terms of water content, all of the major engine manufacturers are clear in stating that water condensate in the fuel gas pipes or engine is NOT acceptable.
Installing a cooling system to dry the gas to a low dew point will ensure that water vapor does not condense in the gas pipe, which helps meet the technical instructions of the major gas engine suppliers.
A Parker Biogas dehumidifaction system
Hydrogen Sulfide (H2S) Removal
Desulphurization of biogas is necessary to prevent corrosion, avoid high toxicity levels, reduce the frequency of engine oil changes, and prevent problems in the combustion process. Depending on the feedstock, H2S levels can vary considerably, with typical concentrations ranging from 100 to 3000 ppm.
There are various processes available for the desulphurization of biogas, the most common being:
1. Biological Oxidation (Bioscrubber)
The simplest of the three processes uses air directly injected into the fermenter and/or a bioscrubber to absorb the sulphur into the washing liquid. This process is often used for the bulk removal of H2S.
2. Chemical Adsorption
Based on chemical reaction of H2S with iron oxide or iron salts, this process can reduce high concentrations of H2S to low levels, but a balance against operating costs needs to be achieved.
3. Physical Adsorption
The most common example of this method is the use of activated carbon, which can be untreated, impregnated or doped to improve efficiency. The high replacement costs make this process more suitable for fine desulphurization or polishing after a biological system.
Siloxanes and VOC Removal
Recent years have seen a marked increase in the use of siloxane-containing products, a substantial amount passing through to waste products both in sewage and landfill sites.
As the gas produced from these sites is used to power biogas-to-energy units, a substantial increase in the effects of the siloxane contamination will be seen in the form of crystalline silicon dioxide (quartz/sand) building up on the combustion surfaces inside generating engines—if the process is left untreated. In addition to damaged engine components, affected engines run inefficiently and produce excessive emissions, particularly carbon monoxide and mono-nitrogen oxides (NOx).
The result is increased operating costs, decreased electricity production and increased pollutants.
There are various technologies commercially available for the removal of siloxanes from biogas. The most common are adsorption-based systems that use media that can be regenerative or non-regenerative.
For lower concentrations of siloxanes, activated carbon is often used as an adsorption media. Activated carbon can remove siloxanes to very low levels, but this method has high operation costs due to the need for the frequent replacement and disposal of hazardous spent media.
For medium to high concentrations of siloxanes, the higher capital investment of a regenerative system is often justified. Regenerative systems can reduce siloxanes to low levels with adsorption media lasting much longer than carbon-based systems. For example, the PpTek BGAK Siloxane Removal System manufactured by Parker (Refer to Figure 4) can guarantee media life of 5 years, during which time siloxane concentrations will remain below 10 mg/m3.
A Parker Regenerative Siloxane Removal System
Raw biogas can be “upgraded” to biomethane, which essentially means it is refined to natural gas quality and can be injected into a gas grid or used as vehicle fuel. To reach pipeline quality, the gas must be upgraded to the correct composition for the gas distribution network to accept.
Prior to upgrading, the gas should be conditioned (see Raw Biogas Treatment) and, in the case of landfill and sewage gas applications, siloxanes and VOCs should be removed (see Siloxane and VOC Removal). The efficient removal of VOCs, such as limonene and other terpenes, is particularly important, as they can mask the odorants added to the upgraded gas as a safety requirement.
The Benefits of Purifying Biogas
The cleaning or purification of biogas involves a complex mix of filtration and separation technologies, but even the most basic of installations can benefit from the advantages of clean, dry gas. For power generation, gas engines are a significant investment in terms of capital and operating costs, making the investment in effective and efficient biogas purification an even more important consideration. This applies even more so for biogas upgrading applications where the processing plants need a high degree of protection from contaminants, and the gas grid specifications strictly insist on clean, dry biomethane before injection can be permitted.
For more information, please contact Kevin Ray, Business Development Manager BioEnergy, Parker Hannifin Corporation, Finite Airtek Filtration Division, tel: 716-686-6582, or visit www.parker.com/hzd or www.parker.com/dhfns
To read more articles on Biogas Industry, please visit www.airbestpractices.com/industries/oil-gas